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Which of the following is not one of the Hückel's criteria for aromaticity?


A) The molecule must be cyclic.
B) The molecule must be planar.
C) The molecule must be completely conjugated.
D) The molecule must have 4n pi electrons.

E) A) and B)
F) A) and C)

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What is the correct assignment of the names of the following substituted benzenes? What is the correct assignment of the names of the following substituted benzenes?   A) I = Phenol; II = anisole; III = toluene B) I = Benzaldehyde; II = phenol; III = anisole C) I = Benzaldehyde; II = phenol; III = toluene D) I = Phenol; II = anisole; III = styrene


A) I = Phenol; II = anisole; III = toluene
B) I = Benzaldehyde; II = phenol; III = anisole
C) I = Benzaldehyde; II = phenol; III = toluene
D) I = Phenol; II = anisole; III = styrene

E) A) and B)
F) A) and C)

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Which of the following is not a criterion for antiaromaticity?


A) The molecule must be cyclic.
B) The molecule must have (4n + 2) pi electrons.
C) The molecule must be planar.
D) The molecule must be completely conjugated.

E) B) and C)
F) None of the above

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Which of the following ions is aromatic? Which of the following ions is aromatic?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) None of the above
F) A) and B)

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Which of the following statements about the structure of benzene is not true?


A) Benzene is planar.
B) Benzene has three short double bonds alternating with three longer single bonds.
C) The electrons in the pi bonds are delocalized around the ring.
D) Benzene has six pi electrons.

E) B) and D)
F) A) and D)

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Where do the protons in benzene appear in the 1H NMR spectrum?


A) Around 1600 cm-1
B) Around 120 ppm
C) Around 0 ppm
D) Around 7 ppm

E) A) and B)
F) None of the above

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?   A) 1-Chloro-4-ethyl-3-propylbenzene B) 1-Chloro-4-ethyl-5-propylbenzene C) 4-Chloro-1-ethyl-2-propylbenzene D) 4-Chloro-2-propyltoluene


A) 1-Chloro-4-ethyl-3-propylbenzene
B) 1-Chloro-4-ethyl-5-propylbenzene
C) 4-Chloro-1-ethyl-2-propylbenzene
D) 4-Chloro-2-propyltoluene

E) A) and B)
F) None of the above

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What orbitals are used to form the indicated bond? What orbitals are used to form the indicated bond?   A) sp<sup>3</sup> B) sp<sup>2</sup> C) p D) sp<sup>3</sup> and sp<sup>2</sup>


A) sp3
B) sp2
C) p
D) sp3 and sp2

E) All of the above
F) B) and C)

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Why is the following compound not aromatic? Why is the following compound not aromatic?   A) It has 4n electrons. B) It is not cyclic. C) It has 4n+2 electrons. D) The pi electron system is not continuous.


A) It has 4n electrons.
B) It is not cyclic.
C) It has 4n+2 electrons.
D) The pi electron system is not continuous.

E) A) and D)
F) A) and C)

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What orbitals are used to form the indicated bond? What orbitals are used to form the indicated bond?   A) sp<sup>3</sup> B) sp<sup>2</sup> C) p D) sp<sup>3</sup> and sp<sup>2</sup>


A) sp3
B) sp2
C) p
D) sp3 and sp2

E) B) and C)
F) A) and C)

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Which of the following heterocycles is not aromatic? Which of the following heterocycles is not aromatic?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and B)
F) A) and C)

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?   A) o-nitrotoluene B) m-nitrotoluene C) p-nitrotoluene D) 3-nitroanisole


A) o-nitrotoluene
B) m-nitrotoluene
C) p-nitrotoluene
D) 3-nitroanisole

E) A) and B)
F) None of the above

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?   A) o-nitroanisole B) m-nitroanisole C) p-nitroanisole D) 2-nitroaniline


A) o-nitroanisole
B) m-nitroanisole
C) p-nitroanisole
D) 2-nitroaniline

E) A) and C)
F) None of the above

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What is the correct assignment of the names of the following substituted benzenes? What is the correct assignment of the names of the following substituted benzenes?   A) I = Styrene; II = aniline; III = anisole B) I = Toluene; II = anisole; III = styrene C) I = Styrene; II = anisole; III = phenol D) I = Toluene; II = aniline; III = anisole


A) I = Styrene; II = aniline; III = anisole
B) I = Toluene; II = anisole; III = styrene
C) I = Styrene; II = anisole; III = phenol
D) I = Toluene; II = aniline; III = anisole

E) All of the above
F) C) and D)

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What is the correct structure for toluene? What is the correct structure for toluene?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and C)
F) None of the above

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What is the correct assignment of the names of the following fused aromatic compounds? What is the correct assignment of the names of the following fused aromatic compounds?   A) I = naphthalene; II = anthracene; III = phenanthrene B) I = naphthalene; II = phenanthrene; III = anthracene C) I = naphthalene; II = phenanthrene; III = benzo[a]pyrene D) I = anthracene; II = naphthalene; III = phenanthrene


A) I = naphthalene; II = anthracene; III = phenanthrene
B) I = naphthalene; II = phenanthrene; III = anthracene
C) I = naphthalene; II = phenanthrene; III = benzo[a]pyrene
D) I = anthracene; II = naphthalene; III = phenanthrene

E) A) and B)
F) A) and C)

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Which of the following compounds is aromatic? Which of the following compounds is aromatic?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and C)
F) B) and C)

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What is the correct structure for 1-bromo-2,4-dimethoxybenzene? What is the correct structure for 1-bromo-2,4-dimethoxybenzene?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) All of the above
F) A) and B)

Correct Answer

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What is the structure of a compound of molecular formula C10H14O2 that shows a strong IR absorption at 3150 ¾2850 cm-1 and gives the following 1H NMR absorptions: 1.4 (triplet,6H) ; 4.0 (quartet,4H) ; and 6.8 (singlet,4H) ppm? What is the structure of a compound of molecular formula C<sub>10</sub>H<sub>14</sub>O<sub>2</sub> that shows a strong IR absorption at 3150 ¾2850 cm<sup>-1</sup> and gives the following <sup>1</sup>H NMR absorptions: 1.4 (triplet,6H) ; 4.0 (quartet,4H) ; and 6.8 (singlet,4H) ppm?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and C)
F) B) and D)

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Why is the following compound not aromatic? Why is the following compound not aromatic?   A) It has 4n pi electrons. B) It is not cyclic. C) It has 4n+2 pi electrons. D) The pi electron system is not continuous.


A) It has 4n pi electrons.
B) It is not cyclic.
C) It has 4n+2 pi electrons.
D) The pi electron system is not continuous.

E) C) and D)
F) A) and B)

Correct Answer

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