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When the atoms involved in a covalent bond have the same electronegativity, what type of bond results?


A) an ionic bond
B) a nonpolar covalent bond
C) a polar covalent bond
D) a hydrogen bond

E) C) and D)
F) A) and C)

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An atom has six electrons in its valence shell. How many single covalent bonds would you expect it to form in most circumstances?


A) one
B) two
C) three
D) six

E) B) and D)
F) B) and C)

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What does it mean to say a system has a AG equal to zero?


A) The system is perfectly ordered no entropy) .
B) The total amount of potential energy in the system is zero.
C) The system is at equilibrium.
D) The system does not release or absorb heat.

E) B) and D)
F) B) and C)

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You need to write down information about a molecule that gives the most accurate picture of the relative sizes of the atoms involved and their relationship in space. Which representation would work best?


A) space- filling model
B) structural formula
C) molecular formula
D) ball- and- stick model

E) C) and D)
F) A) and B)

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Consider the experiment that Stanley Miller did to simulate chemical evolution. Recall that a glass flask held the reduced gases NH3, CH4, and H2 and that the gases were exposed to electrical sparks. What is the null hypothesis in the experiment?


A) Chemical evolution does not occur.
B) Chemical evolution requires the presence of reduced molecules.
C) Chemical evolution occurs only on Earth.
D) Chemical evolution requires a source of kinetic energy.
E) Chemical evolution requires continuous heating.

F) B) and D)
G) C) and D)

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While water has many exceptional and useful properties, which is the rarest property among compounds?


A) Water is a solvent.
B) Water has surface tension.
C) Water has a high heat capacity.
D) Solid water is less dense than liquid water.

E) None of the above
F) A) and B)

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How many electrons are involved in a double covalent bond?


A) one
B) two
C) three
D) four

E) A) and B)
F) All of the above

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Which reaction is most spontaneous?


A) a reaction that is slightly exothermic and leads to a huge increase in entropy
B) a reaction that is slightly endothermic and leads to a huge decrease in entropy
C) a reaction that is highly exothermic and leads to a huge decrease in entropy
D) a reaction that is slightly exothermic and leads to a slight increase in entropy

E) B) and C)
F) None of the above

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Why is water capable of forming hydrogen bonds?


A) It is highly polar.
B) The oxygen atom carries a partial negative charge.
C) The hydrogen atoms carry partial positive charges.
D) All of the above apply.

E) C) and D)
F) B) and D)

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You've been asked to analyze a reaction that took place at 300°K. AH was - 150 and AS was +0.4. Is the reaction endothermic or exothermic?


A) exothermic
B) endothermic
C) You cannot tell unless you know the potential energy of the reactants and products.
D) You cannot tell unless you know the amount of disorder in the reactants and products.

E) None of the above
F) B) and D)

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Which of the following effects is produced by the high surface tension of water?


A) Water flows upward from the roots to the leaves in plants.
B) Lakes don't freeze solid in winter despite low temperatures.
C) A water strider can walk across the surface of a small pond.
D) Evaporation of sweat from the skin helps to keep people from overheating.
E) Organisms resist temperature changes, although they give off heat due to chemical reactions.

F) B) and C)
G) A) and E)

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If an atom is electrically neutral, which of the following must be true?


A) It has the same number of neutrons as electrons.
B) It has the same number of protons as electrons.
C) It has at least one more electron than it has protons.
D) It has the same number of protons as neutrons.

E) B) and D)
F) None of the above

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Experiments by Stanley Miller in the 1950s demonstrated that the first organic molecules on Earth


A) were catalysts composed of simple amino acids and most likely formed in an extraterrestrial environment and were deposited on Earth via asteroids.
B) most likely formed in an extraterrestrial environment and were deposited on Earth via asteroids.
C) were nucleic acids such as RNA and DNA.
D) could have formed abiotically in a reducing atmosphere containing hydrogen, methane, ammonia, and water vapour.
E) were simple carbohydrates like glucose.

F) All of the above
G) A) and D)

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