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What is the hybridization of carbon atoms present in acetylene?


A) sp
B) sp2
C) sp3
D) sp4
E) sp5

F) None of the above
G) A) and D)

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Which theory, valence bond or molecule orbital, correctly predicts the existence of paramagnetic molecules?

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Molecular ...

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What is the hybridization of oxygen atom O? What is the hybridization of oxygen atom O?   A)  sp B)  sp<sup>2</sup> C)  sp<sup>3</sup> D)  sp<sup>4</sup> E)  none


A) sp
B) sp2
C) sp3
D) sp4
E) none

F) A) and B)
G) A) and C)

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s) . For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s) . For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules   -Refer to Diagram 9-1. According to molecular orbital theory, what is the bond order of O<sub>2</sub>-? A)  1 B)  1.5 C)  2 D)  2.5 E)  3 -Refer to Diagram 9-1. According to molecular orbital theory, what is the bond order of O2-?


A) 1
B) 1.5
C) 2
D) 2.5
E) 3

F) A) and B)
G) None of the above

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For which of the following molecules or ions does the central atom have sp hybridization: N3-, O3, and SF3+?


A) N3- only
B) O3 only
C) SF3+ only
D) O3 and SF3+
E) SF3+ and N3-

F) B) and D)
G) A) and B)

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s) . For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s) . For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules   -Refer to Diagram 9-1. Assuming that the molecular orbital energy diagram for a homonuclear diatomic molecule applies to a heteronuclear diatomic molecule, which of the following species is paramagnetic? A)  NO<sup>+</sup> B)  CO C)  CN<sup>-</sup> D)  OF<sup>-</sup> E)  NO -Refer to Diagram 9-1. Assuming that the molecular orbital energy diagram for a homonuclear diatomic molecule applies to a heteronuclear diatomic molecule, which of the following species is paramagnetic?


A) NO+
B) CO
C) CN-
D) OF-
E) NO

F) B) and D)
G) B) and C)

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Which of the underlined atoms (C1, C2, N, and O) are sp2 hybridized? Which of the underlined atoms (C<sub>1</sub>, C<sub>2</sub>, N, and O)  are sp<sup>2</sup> hybridized?   A)  N and O B)  C1 and N C)  C1 and O D)  C2 and N E)  C1 and C2


A) N and O
B) C1 and N
C) C1 and O
D) C2 and N
E) C1 and C2

F) A) and B)
G) A) and C)

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Benzene, C6H6, consists of a six member ring of sp2 hybridized carbon atoms. Each carbon atom has one unhybridized p orbital. How many π2p bonding, antibonding, and nonbonding molecular orbitals exist for benzene?


A) Three π2p molecular orbitals exist; two bonding and one antibonding.
B) Three π2p molecular orbitals exist; one bonding, one antibonding, and one nonbonding.
C) Six π2p molecular orbitals exist; three bonding and three antibonding.
D) Six π2p molecular orbitals exist; two bonding, two nonbonding, and two antibonding.
E) Twelve π2p molecular orbitals exist; six bonding and six antibonding.

F) A) and D)
G) A) and C)

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Which diatomic molecule or ion has valence electron molecular orbital configuration provided below? [core electrons](σ2s) 2(σ*2s) 22p) 22p) 4(π*2p) 3


A) B2
B) O2-
C) O22+
D) Ne2
E) Li2

F) C) and E)
G) B) and D)

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What is the molecular geometry around a central atom that is sp2 hybridized, has three sigma bonds, and one pi bond?


A) trigonal-planar
B) trigonal-pyramidal
C) bent
D) T-shaped
E) tetrahedral

F) A) and D)
G) B) and D)

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SF3+, has a tetrahedral electron-pair geometry and a trigonal-pyramidal molecular geometry. The hybridization of the central sulfur atom is ________.

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If 7 orbitals on one atom overlap 7 orbitals on a second atom, how many molecular orbitals will be formed?


A) 1
B) 2
C) 7
D) 14
E) None of these

F) A) and E)
G) D) and E)

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A molecular orbital that decreases the electron density between two nuclei is said to be ____.


A) hybridized
B) bonding
C) antibonding
D) pi-bonding
E) nonpolar

F) All of the above
G) A) and D)

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For which of the following molecules does the carbon atom have sp3 hybridization?


A) Cl2CO
B) CO
C) CS2
D) CH2Cl2
E) HCN

F) C) and D)
G) D) and E)

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In molecular orbital theory, the bond order is defined as 1/2 × (the number of electrons in ________ orbitals minus the number of electrons in antibonding orbitals).

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In valence bond theory, each sigma bond in CH4 is formed from the overlap of a hydrogen atom's 1s orbital with a(n) ________ hybridized orbital on the carbon atom.

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What is the molecular geometry around an atom that has 2 σ bonds, 2 π bonds, and 0 lone pair of electrons?


A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal

F) B) and C)
G) A) and B)

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The electron configuration of a particular diatomic species is: [core electrons](σ2s) 2(σ*2s) 22p) 22p) 3(π*2p) 0 What is the bond order for this species?


A) 1
B) 1.5
C) 2
D) 2.5
E) 3

F) C) and E)
G) C) and D)

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Which of the following hybridized atoms is impossible to form?


A) An sp hybridized nitrogen atom
B) An sp2 hybridized oxygen atom
C) An sp3 hybridized boron atom
D) An sp3 hybridized phosphorus atom
E) An sp3 hybridized hydrogen atom

F) D) and E)
G) None of the above

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Atomic orbitals combine most effectively to form molecular orbitals when


A) electrons in the orbitals have no spins.
B) electrons in the orbitals have the same spin.
C) the atoms have an equal number of valence electrons.
D) the atomic orbitals have similar energies.
E) only d-orbitals are used in bonding.

F) A) and D)
G) A) and E)

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