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What is the approximate C−C−C bond angle in propene, CH3CH=CH2?


A) 90°
B) 109°
C) 120°
D) 180°

E) A) and D)
F) B) and D)

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Which of the following molecules is not linear?


A) H2O
B) CO2
C) HC≡CH
D) Cl2

E) A) and B)
F) A) and D)

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Circle all of the sp hybridized atoms in the following molecular structure. Circle all of the sp hybridized atoms in the following molecular structure.

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Which atomic orbitals overlap to form the C=O bond of acetone, (CH3) 2C=O?


A) C 2sp3 + O 2sp2
B) C 2sp2 + O 2p
C) C 2sp2 + O 2sp2
D) C 2sp3 + O 2sp

E) B) and D)
F) A) and C)

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What is the approximate value of the length of the C≡C bond in ethyne, HC≡CH?


A) 121 pm
B) 134 pm
C) 142 pm
D) 154 pm

E) All of the above
F) B) and C)

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What is the approximate value of the length of the C=C bond in ethane, CH2=CH2?


A) 121 pm
B) 134 pm
C) 142 pm
D) 154 pm

E) None of the above
F) B) and D)

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Draw bond-line structures of all of the tertiary (3°) alcohols that have the formula C6H14O.

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Which of the following molecules has a molecular dipole moment?


A) H2O
B) CO2
C) HC≡CH
D) Cl2

E) A) and B)
F) A) and C)

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What is the approximate strength of the C−C bond of ethane?


A) 376 kJ/mol (90 kcal./mol)
B) 422 kJ/mol (101 kcal./mol)
C) 556 kJ/mol (133 kcal./mol)
D) 727 kJ/mol (174 kcal./mol)

E) B) and C)
F) A) and B)

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Which of the following molecules has a molecular dipole moment?


A) CO2
B) BF3
C) NH3
D) CH4

E) None of the above
F) B) and C)

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Which atomic orbitals overlap to form the carbon-hydrogen σ bonding molecular orbitals of ethane, CH3CH3?


A) C2p + H1s
B) C2sp + H1s
C) C2sp2 + H1s
D) C2sp3 + H1s

E) B) and D)
F) B) and C)

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The following species forms during an organic reaction. The following species forms during an organic reaction.   The formal charge on the carbon atom indicated by the arrow is +1. The formal charge on the carbon atom indicated by the arrow is +1.

A) True
B) False

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Which of the following resonance structures makes the largest contribution to the structure of [H2CCHO] ? Which of the following resonance structures makes the largest contribution to the structure of [H<sub>2</sub>CCHO] <sup>−</sup>?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) A) and B)

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Which of the following is a secondary (2°) amine? Which of the following is a secondary (2°)  amine?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) All of the above
F) C) and D)

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Which of the following bonds is a polar covalent bond?


A) Na−F
B) C−H
C) C−O
D) Cl−Cl

E) B) and C)
F) None of the above

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Draw bond-line structures of all of the ketones that have the formula C5H10O.

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Which atomic orbitals overlap to form the carbon-carbon σ and π bonding molecular orbitals of ethene, H2C=CH2?


A) C2sp3 + C2sp3, and C2p + C2p
B) C2sp2 + C2sp2, and C2sp2 + C2sp2
C) C2sp2 + C2sp2, and C2p + C2p
D) C2sp3 + C2sp3, and C2sp2 + C2sp2

E) A) and B)
F) A) and C)

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Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in ethyne (acetylene, HC≡CH). Label each bond (e.g., C-H σ bond) and indicate which atomic orbitals contribute to this bond (e.g., C 2sp3 + H 1s).

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The energy released on the addition of an electron to an atom or a molecule is called _____.


A) electron affinity
B) ionization energy
C) resonance energy
D) delocalization

E) A) and B)
F) All of the above

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Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in ethene (ethylene, H2C=CH2). Label each bond (e.g., C-H σ bond) and indicate which atomic orbitals contribute to this bond (e.g., C 2sp3 + H 1s).

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