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Arrange the following solutions in order of increasing boiling point . 0.25 m KCl 0.15 m AlCl3 0.55 m ethanol (CH3CH2OH)


A) (lowest bp) 0.55 m Ethanol m KCl m AlCl3 (highest bp)
B) (lowest bp) 0.15 m AlCl3 m KCl m Ethanol (highest bp)
C) (lowest bp) 0.55 m Ethanol m AlCl3 m KCl (highest bp)
D) (lowest bp) 0.25 m KCl m Ethanol m AlCl3 (highest bp)
E) (lowest bp) 0.25 m KCl m AlCl3 m Ethanol (highest bp)

F) A) and B)
G) D) and E)

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A solution is prepared by mixing 4.00 grams of benzene (molar mass = 78.1 g/mol) , 4.00 grams of CCl4 (molar mass = 153.8 g/mol) , and 4.00 grams of C S2 (molar mass = 76.1 g/mol) . The mole fraction of benzene in this solution is:


A) 0.051
B) 0.200
C) 0.333
D) 0.395
E) 0.605

F) None of the above
G) All of the above

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What is the mole fraction of NH3 for a 5.00% (m/m) aqueous solution of NH3?


A) c NH3 = 0.0527
B) c NH3 = 0.190
C) c NH3 = 0.294
D) c NH3 = 0.810
E) c NH3 = 0.947

F) A) and B)
G) None of the above

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The molarity and molality of a solution:


A) may never be equal.
B) are equal for all solutions.
C) both express the quantity of solute in moles.
D) are equal for all solutions having water as the solvent.
E) are equal for all concentrated solutions.

F) A) and C)
G) A) and B)

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How many grams of NH3 are present in 2.50 L of 3.00 M NH3 solution? MM(NH3) = 17.03 g/mol


A) 0.0705 g NH3
B) 7.50 g NH3
C) 14.2 g NH3
D) 20.4 g NH3
E) 128 g NH3

F) None of the above
G) A) and E)

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An aqueous solution of hydrochloric acid contains 36.0% (m/m) . What is the molality of this same solution? MM(HCl) = 36.46 g/mol and MM(H2O) = 18.015 g/mol


A) 0.217 m
B) 0.563 m
C) 9.87 m
D) 15.4 m
E) 98.7 m

F) C) and D)
G) B) and E)

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At 10 ° C the Henry's law constant for O2 is 1.7×10 - 3 molal/atm. What is the molal concentration of O2 in solution that is in equilibrium with air (20 mole % O2) at 10 ° C?


A) 3.4×10 - 4 m
B) 1.7×10 - 3 m
C) 1.1×10 - 2 m
D) 3.4×10 - 2 m
E) none of these

F) B) and D)
G) B) and C)

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A solution contains 1.00 mole of NaCl in 500 g of water. What is the molal concentration of NaCl?


A) 10.5 m
B) 2.00 m
C) 1.00 m
D) 0.0347 m
E) none of these

F) A) and D)
G) A) and E)

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A quantity of 7.85 g of a compound having the empirical formula C5H4 is dissolved in 301 g of benzene. The freezing point is 1.05 ° C below that of pure benzene (kf = 5.12 ° C/m) . The molar mass of the species in solution in benzene is:


A) 64.0 g/mol
B) 38.3 g/mol
C) 11.5 g/mol
D) 127 g/mol
E) 194 g/mol

F) A) and B)
G) None of the above

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Which aqueous solution would be predicted to have the lowest freezing point?


A) 0.01 m methanol (CH3OH)
B) 0.01 m NaCl
C) 0.01 m KOH
D) 0.01 m Ca(NO3) 2
E) all are the same

F) B) and C)
G) C) and D)

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The solubility of potassium sulfate in water is 6.85 g/100 mL at 0 ° C and 24.1 g/100 mL at 100C. From this we can conclude that:


A) potassium sulfate is an electrolyte.
B) the enthalpy of solution is less than zero.
C) potassium sulfate is insoluble in CH3OH.
D) the enthalpy of solution is positive.
E) none of these

F) B) and C)
G) A) and E)

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After carefully noting the orientation in which water molecules surround each solute particle, which choice below best represents the true nature of how Na2SO4 exists in an aqueous solution?


A) After carefully noting the orientation in which water molecules surround each solute particle, which choice below best represents the true nature of how Na<sub>2</sub>SO<sub>4</sub> exists in an aqueous solution? A)    B)    C)    D)    E)
B) After carefully noting the orientation in which water molecules surround each solute particle, which choice below best represents the true nature of how Na<sub>2</sub>SO<sub>4</sub> exists in an aqueous solution? A)    B)    C)    D)    E)
C) After carefully noting the orientation in which water molecules surround each solute particle, which choice below best represents the true nature of how Na<sub>2</sub>SO<sub>4</sub> exists in an aqueous solution? A)    B)    C)    D)    E)
D) After carefully noting the orientation in which water molecules surround each solute particle, which choice below best represents the true nature of how Na<sub>2</sub>SO<sub>4</sub> exists in an aqueous solution? A)    B)    C)    D)    E)
E) After carefully noting the orientation in which water molecules surround each solute particle, which choice below best represents the true nature of how Na<sub>2</sub>SO<sub>4</sub> exists in an aqueous solution? A)    B)    C)    D)    E)

F) B) and C)
G) B) and D)

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What is the molarity of ions in an aqueous 0.25 M Na3PO4 solution?


A) 0.25 M
B) 0.50 M
C) 1.0 M
D) 1.5 M
E) 2.0 M

F) B) and D)
G) B) and E)

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Which aqueous solution is predicted to have the highest boiling point?


A) 0.03 m CO(NH2) 2, (urea)
B) 0.02 m KCl
C) 0.02 m CaCl2
D) 0.02 m La(NO3) 3
E) insufficient data are given

F) B) and E)
G) A) and E)

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Arrange the following aqueous solutions in order of increasing osmotic pressure . 0.1 M NaCl 0.1 M glucose 0.1 M BaCl2


A) (lowest) 0.1 M NaCl < 0.1 M glucose < 0.1 M BaCl2 (highest)
B) (lowest) 0.1 M NaCl < 0.1 M BaCl2 < 0.1 M glucose (highest)
C) (lowest) 0.1 M glucose < 0.1 M BaCl2 < 0.1 M NaCl (highest)
D) (lowest) 0.1 M glucose < 0.1 M NaCl < 0.1 M BaCl2 (highest)
E) 0.1 M BaCl2 = 0.1 M glucose = 0.1 M NaCl

F) C) and D)
G) A) and B)

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Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210 mL of solution has an osmotic pressure of 0.953 torr at 25 ° C. What is the molar mass of lysozyme?


A) 1.40×104 g/mol
B) 2.94×103 g/mol
C) 1.17×103 g/mol
D) 18.3 g/mol
E) 14.0 g/mol

F) B) and E)
G) None of the above

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What is the molarity of ions in an aqueous 0.50 M Na2SO4 solution?


A) 0.50 M
B) 1.0 M
C) 1.5 M
D) 3.0 M
E) 3.5 M

F) A) and B)
G) C) and D)

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The solubility of a gas in water is highest for:


A) low pressure and low temperature.
B) low pressure and high temperature.
C) high pressure and low temperature.
D) high pressure and high temperature.
E) neither pressure nor temperature changes gas solubility.

F) A) and B)
G) D) and E)

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What mass of CsCl must be added to 0.55 liters of water to produce a 0.430 m solution? Molar Mass(CsCl) = 168.35 g/mol and Density(H2O) = 1.00 g/mL


A) 0.237 g CsCl
B) 0.782 g CsCl
C) 39.8 g CsCl
D) 132 g CsCl
E) 215 g CsCl

F) D) and E)
G) A) and B)

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Which of the following is soluble in H2O?


A) Fe(OH) 3
B) AgI
C) PbSO4
D) NaCl
E) all of them

F) B) and C)
G) A) and D)

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