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Caffeine has the molecular formula, C₈H₁₀ N₄ O₂. If it is burned in excess oxygen it will form carbon dioxide, water vapor, and nitrogen gas. Which gas will be most abundant by mass? 


A)  CO₂
B)  H₂O
C)  N₂
D)  they will all the be the same
E)  it depends on the mass of caffeine

F) C) and D)
G) All of the above

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 Triphenylene is an organic compound containing only carbon and hydrogen with 3 carbon atoms for every two hydrogen atoms.  Which of the following is a possible molecular mass for triphenylene? 


A)  34.0 g/mol
B)  228.29 g/mol
C)  366.8 g/mol
D)  400.0 g/mol
E)  b or c could be correct

F) D) and E)
G) A) and E)

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 A vanadium oxide contains 56.02% vanadium by mass. What is its empirical formula? 


A)  V₂O
B)  VO
C)  V₂O₃
D)  VO₂
E)  V₂O₅

F) D) and E)
G) C) and E)

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You have a compound that contains only carbon and hydrogen. If you burn the compound at high temperature in the presence of oxygen it is completely converted to CO2 and H2O. When you react 20.0 g of your sample you generate 62.7 g of CO2 and 25.7 g of H2O. Which of the following is a possible formula for your compound?


A) C2H2
B) C2H4
C) C2H6
D) C3H5
E) C3H7

F) All of the above
G) A) and B)

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Nitrogen gas reacts with hydrogen gas to produce ammonia. 3 H2(g) + N2(g) → 2 NH3(g) How many grams of nitrogen are required to produce 1.000 g of ammonia?


A) 0.8224
B) 1.644
C) 0.5000
D) 0.6667
E) 0.4112

F) None of the above
G) B) and D)

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 Sodium perbromate can be synthesized via the following reaction that gives off Xenon gas. NaBrO3+XeF2+H2ONaBrO4+2HF+Xe\mathrm{NaBrO}_{3}+\mathrm{XeF}_{2}+\mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{NaBrO}_{4}+2 \mathrm{HF}+\mathrm{Xe} A reaction is started with 200.0g of NaBrO₃, 250.0g of XeF₂ and 100.0g of water.  Assuming that the reaction goes to completion, and that all of the formed xenon gas is allowed to escape into the atmosphere, what will be the minimum mass of products and reactants remaining in the reaction vessel? 


A)  173.4 g
B)  193.9 g
C)  376.0 g
D)  356.1 g
E)  None of the above

F) A) and D)
G) A) and C)

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C

 Calcium carbide, CaC₂, reacts with water to produce calcium hydroxide and acetylene gas, C₂H₂. CaC2(s) +2H2O(l) Ca(OH) 2(aq) +C2H2(g) \mathrm{CaC}_{2}(s) +2 \mathrm{H}_{2} \mathrm{O}(l) \rightarrow \mathrm{Ca}(\mathrm{OH}) _{2}(a q) +\mathrm{C}_{2} \mathrm{H}_{2}(g) How many grams of acetylene can be produced from 30.0 g of calcium carbide? 


A)  1.42 g
B)  12.2 g
C)  28.0 g
D)  30.0 g
E)  64.1 g

F) C) and D)
G) B) and D)

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B

Barium hydroxide reacts with hydrochloric acid to produce barium chloride and water. A balanced chemical equation for this reaction is?


A) Ba(OH) 2 + HCL → BACL2 + H2O
B) Ba(OH) + HCL → BACL + H2O
C) Ba(OH) 2 + 2HCL → BACL2 + 2H2O
D) Ba(OH) 2 + 2HCL → BACL2 + H2O
E) Ba(OH) + 2HCL → BACL + H2O

F) A) and B)
G) A) and C)

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 Aluminum sulfide reacts with water to form aluminum hydroxide and hydrogen sulfide by the following reaction Al2 S3+6H2O2Al(OH) 3+3H2 S\mathrm{Al}_{2} \mathrm{~S}_{3}+6 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{Al}(\mathrm{OH}) _{3}+3 \mathrm{H}_{2} \mathrm{~S} If 25 g of aluminum sulfide is reacted with 25 g of water how many moles of hydrogen sulfide will be formed? 


A)  0.12 moles
B)  0.50 moles
C)  0.78 moles
D)  2.0 moles
E)  3.0 moles

F) A) and D)
G) C) and D)

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Vitamin B12, cyanocobalamin, has the molecular formula, C68H88CoN14O14P. What is the percent mass of cobalt in this compound?


A) 1.02%
B) 4.35%
C) 10.3%
D) 22.3%
E) 23.2%

F) A) and C)
G) A) and D)

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For the given unbalanced reaction X CaO(s) + y H2O(l) → z Ca(OH) 2 The correct stiochiometric coefficients x, y, & z are


A) 1,1,1
B) 1,2,1
C) 2,1,2
D) 2,1,1
E) 1,1,2

F) B) and E)
G) A) and D)

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Tetrasilane (Si4H10) is a liquid with can react with oxygen to form SiO2 and water. How many moles of water are produced from each mole of tetrasilane that reacts?


A) 0.1
B) 2.5
C) 4
D) 5
E) 10

F) C) and D)
G) A) and D)

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 Iron oxide can be reduced to iron by a reaction with carbon to form carbon monoxide Fe2O3(s) +3C(s) 2Fe(s) +3CO(g) \mathrm{Fe}_{2} \mathrm{O}_{3}(s) +3 \mathrm{C}(s) \rightarrow 2 \mathrm{Fe}(s) +3 \mathrm{CO}(g) If 95.0 grams of iron oxide is reacted with excess carbon yields 63 g of iron, what is the percent yield of this reaction?


A)  12%
B)  59%
C)  66%
D)  95%
E)  100%

F) B) and D)
G) C) and D)

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Magnetite is a mineral compound that is 72.36% iron and 27.64% oxygen by mass. What is the empirical formula for the compound that makes up magnetite?


A) FeO
B) Fe2O
C) Fe2O3
D) Fe3O2
E) Fe3O4

F) A) and C)
G) D) and E)

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Assume a kernel of wheat has a volume of 8 mm3. How many moles of wheat kernels can fit in the world's largest grain elevator with a capacity of 20 million bushels (1 bushel = 35.24 L) ?


A) 1.17×10-12
B) 1.42×10-12
C) 1.46×10-10
D) 1.46×10-7
E) 1.42×10-6

F) All of the above
G) A) and C)

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Which of the following is not correctly balanced?


A) 2 Al + 6 HCl → 2 AlCl3 + 3 H2
B) 2 C6H6 + 15 O2 → 12 CO2 + 6 H2O
C) 16 Cr + 3 S8 → 8 Cr2S3
D) 2 NaHCO3 → Na2CO3 + 2 CO2 + H2O
E) Fe2O3 + 2 Al → 2 Fe + Al2O3

F) B) and E)
G) A) and B)

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Magnesium will react with carbon dioxide to form magnesium oxide and carbon. 2 Mg(s) + CO2(g) → 2MgO(s) + C(s) 20) 0 grams of magnesium react completely with excess carbon dioxide. How many grams of solid product should be formed?


A)  20.0 grams
B)  27.5 grams
C)  30.0 grams
D)  38.1 grams
E)  40.0 grams

F) A) and B)
G) A) and C)

Correct Answer

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Which of the following carbohydrates has the largest percent mass of carbon?


A) threose (C4H8O4)
B) ribose (C5H10O5)
C) glucose (C6H12O6)
D) sucrose (C12H22O11)
E) raffinose (C18H32O16)

F) A) and C)
G) B) and D)

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In fermentation, sucrose, C12H22O11, reacts with water to form ethanol, C2H5OH, and carbon dioxide. A balanced chemical equation for this reaction is?


A) C12H22O11(aq) + 3 H2O(l) → 5 C2H5OH(aq) + 2 Co2(g)
B) C12H22O11(aq) + 7 H2O(l) → 2 C2H5OH(aq) + 8 Co2(g)
C) C12H22O11(aq) + 2 H2O(l) → 6 C2H5OH(aq) + Co2(g)
D) C12H22O11(aq) + 2 H2O(l) → 4 C2H5OH(aq) + 4 Co2(g)
E) C12H22O11(aq) + H2O(l) → 4 C2H5OH(aq) + 4 Co2(g)

F) B) and C)
G) A) and B)

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Which has a larger molar volume (the volume occupied by one mole) : gold (density = 19.3 g cm⁻³) or tin (density = 7.31 g cm⁻³) ?


A)  gold
B)  tin
C)  they are exactly the same
D)  there is no way to know without other information

E) B) and C)
F) None of the above

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B

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