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Construct a shell model for calcium, Ca, like Figure 3.9 in the text.

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Calcium has a nuclear charge o...

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Orbitals for which l = 1 are described by which of the following symbols?


A) s
B) p
C) d
D) f
E) g

F) C) and D)
G) All of the above

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If green light has a frequency of 5.0 x 1014 s-1, what is the wavelength (in meters) of this light?


A) 6.7 x 10-24
B) 2.0 x 10-15
C) 6.0 x 10-7
D) 3.0 x 108
E) none of the above

F) B) and E)
G) C) and D)

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C

Arrange the following elements in order of increasing first ionization energy: Ne, Na, Mg


A) Ne < Na < Mg
B) Na < Mg < Ne
C) Ne < Mg < Na
D) Mg < Ne < Na
E) Na < Ne < Mg

F) A) and C)
G) A) and E)

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B

A single atom of element 109 has been synthesized. Predict the electronic configuration of this element. Which of the following elements would 109 most resemble?


A) Ta
B) Re
C) Ir
D) Au
E) Tl

F) B) and D)
G) A) and D)

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Which of the following subshells would be filled first when electrons are added to a gold atom?


A) 4f
B) 5d
C) 6s
D) 6p
E) 6d

F) A) and B)
G) A) and E)

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First ionization energy has been defined as the energy required to remove the most loosely held electron from an electrically neutral atom. Second ionization energy is the minimum energy required to remove an electron from a +1 cation (from an atom that has already lost its first electron). In the same way third ionization energy is the minimum energy to remove an electron from a +2 cation (from an atom that has lost two electrons). Below is a table of first, second, third and fourth ionization energies for Na, Mg and Al. Explain this data for the magnesium atom in terms of its electron configuration. First ionization energy has been defined as the energy required to remove the most loosely held electron from an electrically neutral atom. Second ionization energy is the minimum energy required to remove an electron from a +1 cation (from an atom that has already lost its first electron). In the same way third ionization energy is the minimum energy to remove an electron from a +2 cation (from an atom that has lost two electrons). Below is a table of first, second, third and fourth ionization energies for Na, Mg and Al. Explain this data for the magnesium atom in terms of its electron configuration.

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The first and second electrons are relat...

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Which of the following would have the electron configuration: 1s2 2s2 2p6 3s2 3p6 3d4


A) Ca2+
B) Cr2+
C) Fe2+
D) Ti2+
E) none of these

F) C) and D)
G) A) and D)

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How would you expect the first ionization energy of K to compare to that of Ar?


A) K > Ar
B) K = Ar
C) K < Ar
D) First ionization energies for an atom can vary
E) Ar does not ionize

F) A) and B)
G) A) and E)

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Give the abbreviated electron configuration of platinum, Pt.

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Which of the following wavelengths or frequencies of light will have photons with the highest energy?


A) 450 nm
B) 4.5 x 1014 Hz
C) 600 nm
D) 5.0 x 1014 Hz
E) none of these

F) None of the above
G) B) and C)

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Arrange the following ions in order of decreasing ionic radius.


A) F- > Cl- > Br- > Na+ > Li+
B) Na+ > Li+ > F- > Cl- > Br-
C) Br- > Cl- > F- > Li+ > Na+
D) Br- > Cl- > F- > Na+ > Li+
E) Br-> Cl- >Na+ > F- > Li+

F) A) and E)
G) C) and D)

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Which of the following atoms has a core charge of +6?


A) B
B) C
C) N
D) Si
E) S

F) C) and D)
G) A) and D)

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E

How many electrons can be placed in a 3d orbital?


A) 2
B) 6
C) 8
D) 10
E) 18

F) C) and E)
G) B) and D)

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Calculate the maximum number of electrons that can fit into the n = 4 shell of orbitals.


A) 6
B) 8
C) 18
D) 16
E) 32

F) All of the above
G) A) and C)

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How do Photoelectron spectroscopy experiments differ from experiments used to obtain first ionization energies?

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Experiments to obtain first ionization e...

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A single atom of element 114 was recently synthesized. Predict the electronic configuration of this element. Which of the following elements would 114 most resemble?


A) Au
B) Hg
C) Tl
D) Pb
E) Po

F) A) and E)
G) B) and D)

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What is the wavelength in centimeters of light that has a frequency of 2.33 x 1015 s-1?


A) 6.99 x 1025 cm
B) 7.77 x 104 cm
C) 1.290 x 103 cm
D) 1.29 x 10-5 cm
E) none of the above

F) D) and E)
G) A) and E)

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Photochemistry is when light causes a chemical reaction to occur. A simple example is when light breaks a Cl2 molecule apart into 2 Cl atoms. If the energy required to break apart a mole of chlorine molecules is 243 kJ, a photon of what frequency will break apart a single Cl2 molecule?


A) 6.1 x 1014 s-1
B) 4.0 x 10-19 s-1
C) 3.7 x 1035 s-1
D) 5.2 x 1015 s-1
E) none of the above.

F) A) and E)
G) A) and B)

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O2 molecules can dissociate to form O atoms by absorbing electromagnetic radiation. If it takes 498 kJ to dissociate one mole of O2 molecules to form two moles of O atoms, what is the frequency of the light that would have just enough energy to decompose a single O2 molecule into O atoms?


A) 1.25 x 1015 s-1
B) 8.27 x 10-19 s-1
C) 7.52 x 1038 s-1
D) 8.0 x 10-16 s-1
E) 5.72 x 1016 s-1

F) A) and D)
G) A) and C)

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