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The bond in B2 is longer than the bond in B2-.

A) True
B) False

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below N,N-diethyl-m-tolumide (DEET)  is the active ingredient in many mosquito repellents. What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below    A)  sp B)  sp<sup>2</sup> C)  sp<sup>3</sup> D)  sp<sup>3</sup>d E)  sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) C) and D)
G) B) and C)

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Pi bonds are covalent bonds in which the electron density is concentrated above and below a plane containing the nuclei of the bonding atoms.

A) True
B) False

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Which one of the following molecules is polar


A) PBr5
B) CCl4
C) BrF5
D) XeF2
E) XeF4

F) All of the above
G) C) and D)

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Which one of the following molecules is nonpolar


A) NH3
B) OF2
C) CH3Cl
D) H2O
E) BeCl2

F) D) and E)
G) A) and E)

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In which of the following would the bonding be weakened with the addition of an electron to form the negative molecular ion


A) B2
B) C2
C) N2
D) all of these
E) none of these

F) A) and E)
G) D) and E)

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What is the bond order of Cl2-


A) 0
B) 0.5
C) 1
D) 1.5
E) 2

F) D) and E)
G) C) and D)

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Ibuprofen is used as an analgesic for the relief of pain, and also to help reduce fever. What is the hybridization state of carbon indicated by the arrow in the structure of ibuprofen shown below Ibuprofen is used as an analgesic for the relief of pain, and also to help reduce fever. What is the hybridization state of carbon indicated by the arrow in the structure of ibuprofen shown below   A)  sp B)  sp<sup>2</sup> C)  sp<sup>3</sup> D)  sp<sup>3</sup>d E)  sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and E)
G) All of the above

Correct Answer

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Which one of the following molecules has tetrahedral geometry


A) XeF4
B) BF3
C) AsF5
D) CF4
E) NH3

F) D) and E)
G) B) and E)

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An sp3 hybridized central carbon atom with no lone pairs of electrons has what type of bonding


A) 1 π\pi and 2 σ\sigma bonds
B) 1 π\pi and 3 σ\sigma bonds
C) 2 π\pi and 2 σ\sigma bonds
D) 3 π\pi and 2 σ\sigma bonds
E) 0 π\pi and 4 σ\sigma bonds

F) B) and E)
G) A) and C)

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Ibuprofen is used as an analgesic for the relief of pain, and also to help reduce fever. Ibuprofen is used as an analgesic for the relief of pain, and also to help reduce fever.   How many sigma bonds and pi bonds are contained in an ibuprofen molecule 33 sigma bonds and 4 pi bonds How many sigma bonds and pi bonds are contained in an ibuprofen molecule 33 sigma bonds and 4 pi bonds

A) True
B) False

Correct Answer

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The F - S - F bond angles in SF6 are


A) 90 \circ and 180 \circ .
B) 109.5 \circ .
C) 120 \circ .
D) 180 \circ .
E) 90 \circ and 120 \circ .

F) A) and E)
G) A) and C)

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A molecule with 3 single bonds (and any number of lone pairs) could have which of the following molecular geometries I. Trigonal planar II. Trigonal pyramidal III. Seesaw IV. T-shaped


A) I and II
B) II and III
C) II and IV
D) I and III
E) I, II, and IV

F) A) and B)
G) B) and E)

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A bonding molecular orbital is of lower energy (more stable) than the atomic orbitals from which it was formed.

A) True
B) False

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The N - N - H bond angles in hydrazine N2H4 are 112 \circ . What is the hybridization of the nitrogen orbitals predicted by valence bond theory


A) sp
B) sp2
C) sp3
D) sp4
E) None of the above

F) A) and D)
G) D) and E)

Correct Answer

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A sp hybridized terminal oxygen atom (bonded to one other atom only) with 1 lone pair of electrons has what type of bonding


A) 1 π\pi and 2 σ\sigma bonds
B) 2 π\pi and 1 σ\sigma bonds
C) 2 π\pi and 2 σ\sigma bonds
D) 0 π\pi and 2 σ\sigma bonds
E) 0 π\pi and 3 σ\sigma bonds

F) C) and E)
G) A) and E)

Correct Answer

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The BrF5 molecule has polar bonds and has a net dipole moment.

A) True
B) False

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Which of the following correctly lists species in order of increasing bond length


A) O2 < O2+ < O2-
B) O2- < O2 < O2+
C) O2+ < O2 < O2-
D) O2- < O2+ < O2
E) O2+ < O2- < O2

F) C) and D)
G) All of the above

Correct Answer

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents.   There are 30 sigma bonds and 4 pi bonds are contained in a DEET molecule. There are 30 sigma bonds and 4 pi bonds are contained in a DEET molecule.

A) True
B) False

Correct Answer

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Ozone (O3) is an allotropic form of oxygen. According to VSEPR theory the shape of the ozone molecule is bent.

A) True
B) False

Correct Answer

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