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A species with a bond order of 1/2 may be stable.

A) True
B) False

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Indicate the type of hybrid orbitals used by the central atom in TeF4.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) D) and E)
G) A) and C)

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In which of the following would the bonding be weakened with the addition of an electron to form the negative molecular ion?


A) N2
B) O2
C) F2
D) all of these
E) none of these

F) None of the above
G) All of the above

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According to VSEPR theory, which of the following triatomic ions should be linear: N3-, I3-, NO2-, ClO2-, SCN-?

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N3-, I3-, and ...

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The bond angles in SF5+ are expected to be


A) 90°.
B) 120°.
C) 90° and 120°.
D) 90° and 180°.
E) 90°, 120°, and 180°.

F) A) and B)
G) C) and E)

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E

According to the VSEPR theory, the molecular geometry of ammonia is


A) linear.
B) trigonal planar.
C) bent.
D) tetrahedral.
E) trigonal pyramidal.

F) B) and D)
G) B) and E)

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Give the number of lone pairs around the central atom and the geometry of the ion SeO42-.


A) 0 lone pairs, square planar
B) 0 lone pairs, tetrahedral
C) 1 lone pair, distorted tetrahedron (seesaw)
D) 1 lone pair, square pyramidal
E) 2 lone pairs, square planar

F) C) and E)
G) All of the above

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Give the number of lone pairs around the central atom and the geometry of the ion IBr2-.


A) 0 lone pairs, linear
B) 1 lone pair, bent
C) 2 lone pairs, bent
D) 3 lone pairs, bent
E) 3 lone pairs, linear

F) A) and B)
G) A) and C)

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Which of the following substance is/are planar? (i) SO3 (ii) SO32- (iii) NO3- (iv) PF3 (v) BF3


A) only (i) and (ii)
B) only (i) , (iii) , and (v)
C) only (iv)
D) all are planar except (iv)
E) all are planar except (ii)

F) None of the above
G) D) and E)

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The N - N - H bond angles in hydrazine N2H4 are 112°. What is the hybridization of the nitrogen orbitals predicted by valence bond theory?

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Predict the geometry around the central atom in XeO4.


A) trigonal planar
B) trigonal pyramidal
C) tetrahedral
D) trigonal bipyramidal
E) octahedral

F) A) and E)
G) A) and B)

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C

Which one of the following molecules is polar?


A) PBr5
B) CCl4
C) BrF5
D) XeF2
E) XeF4

F) A) and E)
G) A) and D)

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In which of the following would the bonding be strengthened with the addition of an electron to form the negative molecular ion?


A) N2
B) O2
C) F2
D) all of these
E) none of these

F) All of the above
G) A) and C)

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Which of the following molecules have the same geometries?


A) SF4 and CH4
B) CO2 and H2O
C) CO2 and BeH2
D) N2O and NO2

E) A) and D)
F) B) and D)

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In which one of the following molecules is the central atom sp2 hybridized?


A) SO2
B) N2O
C) BeCl2
D) NF3
E) PF5

F) B) and C)
G) A) and E)

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A bonding molecular orbital is of lower energy (more stable)than the atomic orbitals from which it was formed.

A) True
B) False

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The bond angle in ICl2- is expected to be


A) a little less than 109.5°.
B) 109.5°.
C) a little more than 109.5°.
D) 120°.
E) 180°.

F) C) and D)
G) None of the above

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E

Use VSEPR theory to predict the molecular geometry of CO32-.

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Give the number of lone pairs around the central atom and the molecular geometry of SCl2.


A) 0 lone pairs, linear
B) 1 lone pair, bent
C) 2 lone pairs, bent
D) 3 lone pairs, bent
E) 3 lone pairs, linear

F) A) and C)
G) None of the above

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According to the VSEPR theory, the molecular geometry of SiCl4 is


A) linear.
B) trigonal planar.
C) bent.
D) tetrahedral.
E) trigonal pyramidal.

F) C) and E)
G) A) and E)

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