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The number of pi bonds in the molecule below is The number of pi bonds in the molecule below is   A) 1. B) 2. C) 3. D) 5. E) 9.


A) 1.
B) 2.
C) 3.
D) 5.
E) 9.

F) None of the above
G) A) and B)

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Predict the geometry around the central atom in SO42-.


A) trigonal planar
B) trigonal pyramidal
C) tetrahedral
D) trigonal bipyramidal
E) octahedral

F) A) and B)
G) D) and E)

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Using periodic trends, arrange the following molecules in order of increasing dipole moment: NH3, PH3, AsH3.

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Predict the molecular geometry and polarity of the SO2 molecule.


A) linear, polar
B) linear, nonpolar
C) bent, polar
D) bent, nonpolar
E) None of the above.

F) A) and B)
G) A) and C)

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Which one of the following molecules has a non-zero dipole moment?


A) BeCl2
B) Br2
C) BF3
D) IBr
E) CO2

F) B) and D)
G) None of the above

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The hybridization of B in the BF3 molecule is sp3.

A) True
B) False

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Consider the species N2-, N2, and N2+. Which of these species will be paramagnetic?


A) N2 and N2-
B) N2+ and N2
C) N2+ and N2-
D) only N2-
E) none are paramagnetic

F) A) and E)
G) A) and D)

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of the nitrogen atom in the structure of DEET shown below? N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of the nitrogen atom in the structure of DEET shown below?   A) sp B) sp<sup>2</sup> C) sp<sup>3</sup> D) sp<sup>3</sup>d E) sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) B) and E)

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According to VSEPR theory, which one of the following molecules has tetrahedral geometry?


A) NH3
B) CCl4
C) CO2
D) SF4
E) PCl5

F) B) and C)
G) All of the above

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According to the VSEPR theory, the actual F -As -F bond angles in the AsF4- ion are predicted to be


A) 109.5°.
B) 90° and 120°.
C) 180°.
D) < 109.5°.
E) < 90° and < 120°.

F) A) and E)
G) D) and E)

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below? N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below?   A) sp B) sp<sup>2</sup> C) sp<sup>3</sup> D) sp<sup>3</sup>d E) sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) C) and D)
G) None of the above

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Predict the geometry and polarity of the CS2 molecule.


A) linear, polar
B) linear, nonpolar
C) tetrahedral, nonpolar
D) bent, nonpolar
E) bent, polar

F) C) and E)
G) A) and C)

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What is the hybridization of As in the AsF4- ion?


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) B) and D)
G) A) and B)

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Indicate the type of hybrid orbitals used by the central atom in PCl3.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) B) and C)
G) A) and E)

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The F - S - F bond angles in SF6 are


A) 90° and 180°.
B) 109.5°.
C) 120°.
D) 180°.
E) 90° and 120°.

F) B) and C)
G) D) and E)

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The hybridization of the central nitrogen atom in the molecule N2O is


A) sp.
B) sp2.
C) sp3.
D) sp3d.
E) sp3d2.

F) A) and C)
G) A) and D)

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Which of the following molecules should be polar? a. CH3OH b. H2O c. CH3OCH3

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All of the...

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The number of pi bonds in the oxalate ion (C2O42-) is


A) 1.
B) 2.
C) 3.
D) 4.
E) 5.

F) A) and B)
G) All of the above

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What is the hybridization of the As atom in the AsF5 molecule?


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) C) and D)
G) A) and E)

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Pi bonds are covalent bonds in which the electron density is concentrated above and below a plane containing the nuclei of the bonding atoms.

A) True
B) False

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