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Which reagents would be used in a Mannich reaction to synthesize Which reagents would be used in a Mannich reaction to synthesize   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and B)
G) All of the above

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Which of the following would afford the best synthesis of diethyl phenylmalonate, Which of the following would afford the best synthesis of diethyl phenylmalonate,   A)    B)    C)    D)    E)


A)
Which of the following would afford the best synthesis of diethyl phenylmalonate,   A)    B)    C)    D)    E)
B)
Which of the following would afford the best synthesis of diethyl phenylmalonate,   A)    B)    C)    D)    E)
C)
Which of the following would afford the best synthesis of diethyl phenylmalonate,   A)    B)    C)    D)    E)
D)
Which of the following would afford the best synthesis of diethyl phenylmalonate,   A)    B)    C)    D)    E)
E)
Which of the following would afford the best synthesis of diethyl phenylmalonate,   A)    B)    C)    D)    E)

F) A) and C)
G) B) and E)

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Which reagents would you use to synthesize this compound by an aldol condensation? Which reagents would you use to synthesize this compound by an aldol condensation?   A)    B)    C)    D)    E)


A)
Which reagents would you use to synthesize this compound by an aldol condensation?   A)    B)    C)    D)    E)
B)
Which reagents would you use to synthesize this compound by an aldol condensation?   A)    B)    C)    D)    E)
C)
Which reagents would you use to synthesize this compound by an aldol condensation?   A)    B)    C)    D)    E)
D)
Which reagents would you use to synthesize this compound by an aldol condensation?   A)    B)    C)    D)    E)
E)
Which reagents would you use to synthesize this compound by an aldol condensation?   A)    B)    C)    D)    E)

F) C) and D)
G) B) and C)

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What would be the product of the following sequence? What would be the product of the following sequence?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and B)
G) A) and C)

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The aldol reaction of cyclohexanone produces which of these self-condensation products? The aldol reaction of cyclohexanone produces which of these self-condensation products?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) D) and E)
G) All of the above

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When α\alpha , β\beta -unsaturated aldehydes and ketones react with nucleophiles,simple addition is favored when _________ nucleophiles are used,while conjugate addition is preferred by ___________ nucleophiles.

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Which of these is a product of the reaction of C6H5MgBr with Which of these is a product of the reaction of C<sub>6</sub>H<sub>5</sub>MgBr with   A)    B)    C)    D)    E)


A)
Which of these is a product of the reaction of C<sub>6</sub>H<sub>5</sub>MgBr with   A)    B)    C)    D)    E)
B)
Which of these is a product of the reaction of C<sub>6</sub>H<sub>5</sub>MgBr with   A)    B)    C)    D)    E)
C)
Which of these is a product of the reaction of C<sub>6</sub>H<sub>5</sub>MgBr with   A)    B)    C)    D)    E)
D)
Which of these is a product of the reaction of C<sub>6</sub>H<sub>5</sub>MgBr with   A)    B)    C)    D)    E)
E)
Which of these is a product of the reaction of C<sub>6</sub>H<sub>5</sub>MgBr with   A)    B)    C)    D)    E)

F) C) and D)
G) All of the above

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What is the final product of the following reaction sequence? Give structural details of all significant intermediates. What is the final product of the following reaction sequence? Give structural details of all significant intermediates.

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  -Consider the synthesis above in answering this question.What is compound A? A)  Butanone B)  Butanal C)  Propanal D)  1-Butanol E)  2-Methylpropanal -Consider the synthesis above in answering this question.What is compound A?


A) Butanone
B) Butanal
C) Propanal
D) 1-Butanol
E) 2-Methylpropanal

F) None of the above
G) A) and E)

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What is the final product of the following reaction sequence? Give structural details of all significant intermediates. What is the final product of the following reaction sequence? Give structural details of all significant intermediates.

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What final product is obtained when 2,8-nonanone is treated with base,followed by reaction with sodium borohydride? What final product is obtained when 2,8-nonanone is treated with base,followed by reaction with sodium borohydride?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) D) and E)
G) B) and C)

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What would be the major product of the following reaction? What would be the major product of the following reaction?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) All of the above
G) C) and E)

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The sequence of a Michael addition followed by an intramolecular aldol condensation is known as a ___________.

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What would be the major product of the following reaction? What would be the major product of the following reaction?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) C) and D)
G) A) and B)

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Which is the only one of these compounds which cannot self-condense in the presence of dilute aqueous alkali?


A) Phenylethanal
B) Propanal
C) 2-Methylpropanal
D) 3-Methylpentanal
E) 2,2-Dimethylpropanal

F) A) and B)
G) A) and C)

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Esters frequently react in the presence of alkoxides by a reaction called the __________ condensation.

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The reaction of The reaction of   with base affords which of these products?   A)  I B)  II C)  III D)  IV E)  V with base affords which of these products? The reaction of   with base affords which of these products?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and E)
G) C) and E)

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  -What is the intermediate B in the synthesis shown above?   A)  I B)  II C)  III D)  IV E)  V -What is the intermediate B in the synthesis shown above?   -What is the intermediate B in the synthesis shown above?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and B)
G) A) and C)

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What product is formed during the following reaction? What product is formed during the following reaction?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) C) and E)
G) C) and D)

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What would be the major product of the following reaction? What would be the major product of the following reaction?   A)    B)    C)    D)    E)


A)
What would be the major product of the following reaction?   A)    B)    C)    D)    E)
B)
What would be the major product of the following reaction?   A)    B)    C)    D)    E)
C)
What would be the major product of the following reaction?   A)    B)    C)    D)    E)
D)
What would be the major product of the following reaction?   A)    B)    C)    D)    E)
E)
What would be the major product of the following reaction?   A)    B)    C)    D)    E)

F) A) and B)
G) A) and C)

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